Talha's Physics Academy
Boyle's Law: Statement, Derivation & Graphs
State and Explain Boyle’s Law. Also draw its graphs.
Statement
"The volume of a fixed mass of a gas is inversely proportional to its pressure, provided its temperature remains constant."
Mathematical Derivation
If $P$ represents the pressure exerted on the surface of the gas and $V$ represents the volume of the gas, then mathematically at constant temperature:
$V \propto \frac{1}{P} \quad \text{or} \quad V = \frac{k}{P} \quad \Rightarrow \quad PV = k \quad (\text{constant})$
Let $P_1$ and $V_1$ represent the initial pressure and initial volume of a gas. If at a constant temperature we increase the pressure from $P_1$ to $P_2$, its volume will decrease from $V_1$ to $V_2$:
- At initial state: $P_1 V_1 = k$ --- (i)
- At final state: $P_2 V_2 = k$ --- (ii)
Equating equations (i) and (ii), since the constant $k$ remains unchanged for a fixed mass of gas at constant temperature:
$$P_1 V_1 = P_2 V_2$$
Fig: Effect of increasing pressure on gas volume in a cylinder piston model ($P_2 > P_1$, $V_2 < V_1$).
Graphical Representation
The relationship described by Boyle's law can be represented graphically in two standard ways:
- (a) $P\text{-}V$ Graph: The curve between pressure ($P$) and volume ($V$) shows that if pressure increases, volume decreases and vice versa (forming a rectangular hyperbola).
- (b) $P\text{-}\frac{1}{V}$ Graph: The graph plotted between pressure ($P$) and inverse volume ($\frac{1}{V}$) yields a straight line passing through the origin, confirming direct proportionality between $P$ and $\frac{1}{V}$.
Fig: Graphical representation of Boyle's Law showing (a) inverse curved relationship and (b) linear direct proportionality with inverse volume.
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